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Calorific Values of Woods and other Biofuels

Table of contents:

The table below gives the calorific values of various woods and other biofuels, burned in ideal conditions, so enough oxygen for full combustion and no kiln inefficiencies.

The heat available from a fully dried fuel is the gross calorific value. But in practice there will always be some water present, which consumes 2440 kJ/kg to get to boiling point and evaporate off. Subtracting the energy needed to eliminate the water results in the nett calorific value. The upper value in the table is of dry fuel, and the lower value is with a higher level of moisture.

The calorific value of oven dried woods (i.e. as dry as is reasonably possible - 0% in a lab, but in practice 5% at best) varies very little between species, at 18500 - 19000 kJ/kg. Softwoods are about 2% higher than hardwoods. This is primarily due to a higher lignin content (which releases 26000 - 27000 kJ/kg) compared to cellulose (17200 - 17500 kJ/kg) and hemicellulose (16000 kJ/kg). Secondary to this, conifers are also helped by the higher content of resin, wax and oil. Also some species have a higher hydrogen content, which releases more heat, and other have a higher ash content, which reduces the heat release per kg. Herbaceous plants are about 9% lower, and overall biofuels are in the range of 16500 - 19000 kJ/kg.

If we measure the moisture content of the wood, then we can calculate it's calorific value:
Given
M, the moisture content (%) of the wood
NCVO, the calorific value of the wood when fully oven dried (which we can assume to be 19000 kJ/kg if we don't have specific data for that species)
then the calorific value at moisture level M (NCVO) is given by:
NCVM = (NCVO x (100 - M) - 2.44xM)/100
So, for example, if we have wood at 40% moisture content the calorific value is:
(19000 x (100 - 40) - 2.44 x 40) / 100 = (19000 x 60 - 97.6) / 100 = 11399012.4 / 100 = 113990 kJ/kg - about 40% lower than fully dried wood.

When considering the moisture content of your wood, you have to remember that wood will absorb (and expel) moisture to work towards that of the surrounding air. So there's little point in oven drying wood and then stacking it outdoors in a humid environment.

MaterialLower (kJ/kg)Upper (kJ/kg)
Alfalfa1703018500
Bamboo1900019800
Birch wood1870020100
Cedar bark1980021100
Cherry wood1790019100
Coconut trunk wood1660017800
Corn stalks/stover1680018500
Cotton gin trash1520016000
Cotton stalks1700018300
Cypress wood2150023000
Douglas fir bark2080022100
Douglas fir wood1970021000
Elm wood1900020500
Eucalyptus bark1730018500
Eucalyptus wood1830019600
Flax1780018800
Grass1700018100
Hardwood bark1830019600
Hardwood1860020700
Hay1620018300
Hemp1650017600
Jute stick1780019400
Larch wood1870020100
Lucerne1770019000
Maple wood1870020000
Miscantus/Napier grass1780019100
Oak bark1830019300
Oak wood1740018800
Pine bark1970021000
Pine wood1950020800
Poplar wood1940020800
Rice husk1420015400
Rice straw1350014800
Softwood1750021100
Spruce bark1910020300
Spruce wood1850019800
Sugar cane bagasse1770019400
Switchgrass1680019100
Teak wood1890020200
Wheat straw1500018900
Willow wood1730018600